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Zirconia-ceramic coupling agents (Z-CAs) are ceramic primers which contain zirconia particles and which are used to bond ceramic cores and metal veneers. They are less expensive, stronger, more durable and efficient than metal-ceramic coupling agents.

Chemical Composition of Z-CAs

Zirconia-ceramic coupling agents (Z-CAs) are ceramic primers which contain zirconia particles and which are used to bond ceramic cores and metal veneers. They are less expensive, stronger, more durable and efficient than metal-ceramic coupling agents.

Zirconia particles are ceramic powders typically with a size range of 0.5-4.0 µm. Particles can be made of single crystal (monoclinic), zirconium oxide (tetragonal), calcium oxide and manganese oxide. The Z-CAs may contain other ceramic additives such as aluminium oxide, silicon dioxide, magnesium oxide, borosilicate glass and sodium borosilicate glass. The Z-CAs are typically applied to metal surfaces (oxides such as titanium, zirconium, hafnium, niobium, tantalum) at a ratio of 20-40 wt %.

Advantages of Zirconia-Ceramic Coupling Agents

The major advantages of Z-CAs are:

Economical – Z-CAs are less expensive than all-ceramic crowns compared to machinability.

Stress Transfer – Zirconia particles are effective stress dissipators and can transfer the load to the tooth.

Long term performance – Z-CAs provide long lasting bonds between the core and veneer due to longer useful life than metal-ceramic crowns.

High fracture toughness – Z-CAs provide higher fracture toughness than all-ceramic crowns.

Advantages of Interlocking Zirconia-Ceramic Crowns

The major advantage of Zirconia-Ceramic Interlocking crowns is their high reliability. Interlocking crown

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